Module Identifier 
PH32010 
Module Title 
SPECTROSCOPY 
Academic Year 
2003/2004 
Coordinator 
Professor Keith Birkinshaw 
Semester 
Semester 1 
Other staff 
Dr Tudor E Jenkins 
PreRequisite 
PH21010 , PH23010 
Course delivery 
Lecture  22 lectures 

Other  Workshop. 2 example classes 
Assessment 
Assessment Type  Assessment Length/Details  Proportion 
Semester Exam  3 Hours end of semester examination for MPhys students  80% 
Semester Exam  2 Hours end of semester examination for BSc students  80% 
Semester Assessment  Course Work: Examples Class 2 Deadline (by week of semester): week 9  10% 
Semester Assessment  Course Work: Examples Class 1 Deadline (by week of semester): week 4  10% 

Learning outcomes
After taking this module students should be able to:

perform a vector addition of angular momenta using LS or jj coupling scheme.

calculate energy level shifts in a magnetic field.

classify states of single and multielectron atoms.

predict allowed transitions from selection rules.
Brief description
A familiarity with the spectrum of hydrogen atoms is expected. A brief recap of relevant aspects of prerequisite courses is followed by the relevant aspects of the underlying quantum mechanics. The spectra of H atoms, alkali metals and alkaline earths and the influence of external magnetic fields (Zeeman effect) provide the data for the study of parameters influencing atomic energy levels and transitions between them. The coupling of orbital and spin angular momenta, the Pauli Exclusion Principal, etc., are discussed and the specification of electronic states is explained. Selection rules and their consequences are presented.
Content
ATOMS
Spectroscopy of the H atom  gross, fine and hyperfine structure; underlying quantum theory including Schrodingers equation, quantum numbers n, l, m1.
Spin, spinorbit coupling, total angular momentum in a single electron atom.
Many electron atoms  the Pauli Exclusion Principle.
LS coupling and jj coupling.
Electron configuration, term symbols, Hund's rules.
Alkali and alkali earth spectra.
Helium and configuration interaction.
Zeeman effect  space quantisation.
Radiative transitions and selection rules.
Width and intensity of spectral lines.
Fine and hyperfine structure  nuclear spin.
Rydberg states.
Transferable skills
Tutorials
Examples classes
Reading Lists
Books
** Reference Text
Gerhard Herzberg Atomic Spectra and Atomic Structure
Dover
AP Thorne Spectrophysics
Chapman and Hall
PW Atkins Physical Chemistry
Oxford University Press ISBN 019855284X
** Should Be Purchased
TP Softley Atomic Spectra
OUP ISBN 0198556888
Notes
This module is at CQFW Level 6