# Module Information

#### Course Delivery

Delivery Type | Delivery length / details |
---|---|

Lecture | 18 lectures |

Seminars / Tutorials | 2 tutorials |

#### Assessment

Assessment Type | Assessment length / details | Proportion |
---|---|---|

Semester Exam | 2 Hours Written Examination | 70% |

Semester Assessment | Course Work: Example Sheets. Deadlines are detailed in the Year 2 Example Sheet Schedule distributed by the Department. | 30% |

Supplementary Exam | 2 Hours Written Assessment | 100% |

### Learning Outcomes

After taking this module students should be able to:

- understand the principles of the zeroth, first and second laws of thermodynamics and apply the three laws to solve associated problems
- explain diffusion, heat conduction and viscosity in terms of transport properties
- calculate quantities given by kinetic theory e.g. effusion rate, collision frequency etc.
- explain variations of heat capacity of gases with temperature in terms of population of energy levels
- identify the principal thermodynamic steps in the operation of heat engines and calculate efficiencies
- be familiar with the basic concepts of reversibility and entropy.

### Brief description

Thermal Physics deals with material properties and processes related to the conversion of heat and work and vice versa. Thermal processes can be understood at the atomic as well as the macroscopic level, and both approaches are introduced here. The laws of thermodynamics have been derived from empirical observations of gases, but they are applicable universally. The concepts of heat, work, reversibility, entropy and the steady state are central to many other areas of physics. Thermal Physics can explain the workings of heat engines, refrigerators and power stations by balancing the heat and work exchanged in each step of their operation cycle. On the atomic level, pressure can be understood as the summed impact of the collisions of gas molecules on the container walls. This is the idea of the kinetic theory, which leads to the thermal distribution of velocities and more generally to the population of energy levels. Many processes are irreversible, showing that an energy balance is not sufficient to predict the direction of a process. Entropy is introduced to take into account the dissipative nature of irreversible processes and to quantify the influence of disorder on the probability of a process.

### Content

- ideal gas:

- ideal gas laws

- real gases

- Virial equation, Boyle temperature, critical point

- Van der Waals equation, Maxwell construction

- kinetic theory of gases:

- Maxwell-Boltzmann, rms-mean-probable speed

- temperature and population of energy levels

- zeroth law:

- temperature and temperature scales

- thermal expansion

- first law:

- isothermal, isobaric, and adiabatic processes

- heat capacity, latent heat

- second law:

- Kelvin-Planck, Clausius statements

- reversible and irreversible processes

- Carnot cycle

- thermodynamic temperature scale

- entropy:

- entropy and probability

- the Helmhotte function, partition function

- transport properties:

### Reading List

**General Text**

C.B.P. Finn Thermal Physics Nelson-Thornes (previously published with Routledge) Primo search

**Should Be Purchased**

P.A. Tipler Physics for Scientists and Engineers W.H. Freeman 1999 Primo search

**Recommended Text**

P.W. Atkins Physical Chemistry Oxford Press Primo search

### Notes

This module is at CQFW Level 5